Ukraine beat Finland (82-76) for their first victory of the tournament and moved into fourth place. Olena Zherzherunova was once again the leading player for Ukraine with 22 points and 11 rebounds.
Finland were led by Taru Tuukkanen with 28 points and 11 rebounds as her team ended the competition in bottom place.
In the final game in Group A, Bulgaria held off the Netherlands (70-62) to clinch second place. Donneka Hodges was the top scorer again for Bulgaria with 19 points while Jaklin Zlatanova just missed a double-double with 9 points and 11 rebounds.
For the Netherlands the Limoges player Tanya Bröring was the only player in double digits with 17 points.
In Group B, the hosts Italy, led by Simona Ballardini, outscored Romania (76-60) while Serbia cruised past Belgium (82-70).
Italy finished second place with three victories while Serbia took third place. Belgium had to settle for fourth while Romania were left with the wooden spoon.
Results from day 5
Finland 76-82 Ukraine Netherlands 62-70 Bulgaria Romania 60-76 Italy Belgium 70-82 Serbia
The games between Germany and Hungary for the last European Championship place in 2011 spot will be played on 12 and 15 June.